Compd.

Feature

m.p./˚C

Yield*(%)

LRMS (EI, 70 eV), m/z (%)

HRMS (ESI) [M+H]+(calcd.), m/z

IR (KBr)

ν/cm−1

4a,5a

Yellow solid

278.6

93

249 (18), 247 (10), 220 (100), 105(53)

249.1033

(249.1023)

3257, 1625, 1464, 1298, 1288, 1171, 909, 759, 686

4a,5a

Yellow solid

278.6

93

249 (18), 247 (10), 220 (100), 105 (53)

249.1033

(249.1023)

3257, 1625, 1464, 1298, 1288, 1171, 909, 759, 686

4b,5b

Yellow solid

184.6

73

276 (96), 248 (100), 130 (10), 119 (75)

277.1341

(277.1335)

3274, 1618, 1455, 1374, 1291, 1271, 1169, 906, 769, 702

4c,5c

Yellow solid

187.4

80

309 (17), 308 (78), 265 (28), 135 (100)

309.1243

(309.1234)

3263, 1611, 1599, 1450, 1288, 1247, 1160, 1029, 905, 831, 775, 657

4d,5d

Yellow solid

113.0

83

285 (17), 284 (100), 135 (74), 95 (51)

285.0831

(285.0834)

3248, 1627, 1469, 1385, 1310, 1289, 1264, 1245, 1170, 1040, 940, 868, 761, 680

4e,5e

Yellow solid

171.0

58

318 (50), 316 (77), 207 (53), 139 (100)

317.0257

(317.0243)

3269, 2921, 2847, 1614, 1584, 1469, 1451, 1292, 1168, 1100, 1015, 904, 835, 771

4f,5f

Brown solid

257.9

69

408 (48), 406 (100), 380 (39), 157 (67)

404.9243

(404.9233)

3257, 2914, 1679, 1580, 1451, 1320, 1169, 1071, 1022, 1012, 903, 832, 770, 713, 665

4g,5g

Brown solid

272.3

65

298 (66), 270 (100), 130 (72), 102 (84)

299.0944

(299.0928)

3280, 2217, 1635, 1607, 1464, 1320, 1301, 1177, 1146, 914, 768, 681

4h,5h

Yellow solid

200.6

52

385 (16), 384 (78), 356 (100), 173 (42)

385.0769

(385.0770)

3274, 1632, 1615, 1478, 1328, 1292, 1169, 1112, 1065, 1014, 910, 785, 682