选点个数 | WHO对照品 | EP对照品 | ||
保留时间(min) | 分子量 | 保留时间(min) | 分子量 | |
1 | 13.421 | 18,000 | 13.808 | 14,314 |
2 | 13.713 | 15,600 | 14.217 | 12,801 |
3 | 14.063 | 13,600 | 14.617 | 11,069 |
4 | 14.404 | 12,000 | 15.008 | 9859 |
5 | 15.079 | 9600 | 15.400 | 8943 |
6 | 15.529 | 8400 | 15.775 | 7841 |
7 | 16.063 | 7200 | 16.133 | 7007 |
8 | 16.354 | 6600 | 16.343 | 6661 |
9 | 16.671 | 6000 | 16.628 | 6071 |
10 | 17.012 | 5400 | 16.961 | 5559 |
11 | 17.363 | 4800 | 17.437 | 4841 |
12 | 17.746 | 4200 | 17.726 | 4128 |
13 | 18.154 | 3600 | 18.240 | 3482 |
14 | 18.588 | 3000 | 18.605 | 3053 |
15 | 19.063 | 2400 | 19.101 | 2421 |
16 | 19.604 | 1800 | 19.664 | 1860 |
17 | 20.271 | 1200 | 20.298 | 1247 |
18 | 21.246 | 600 | 21.254 | 583 |
校正曲线 | logM = −0.00275648T3 + 0.1320164T2 − 2.238323T + 17.17206 | logM = − 0.002832371T3 + 0.1349939T2 − 2.269252T + 17.21699 | ||
相关系数R | 0.99995 | 0.99978 | ||
离差 | 0.0038896 | 0.0074436 |