Entry | Cat. | Solvent | t/h | Yieldb/% |
1 | None | H2O | 12 | - |
2 | MCM-41 | H2O | 12 | - |
3 | PW | H2O | 12 | 15 |
4 | PM | H2O | 12 | 10 |
5 | 20 wt% PW/MCM-41 | H2O | 12 | 25 |
6 | 50 wt% PW/MCM-41 | H2O | 12 | 36 |
7 | 60 wt% PW/MCM-41 | H2O | 12 | 36 |
8 | 70 wt% PW/MCM-41 | H2O | 12 | 29 |
9 | 80 wt% PW/MCM-41 | H2O | 12 | 30 |
10 | 50 wt% PM/MCM-41 | H2O | 12 | 25 |
11 | 50 wt% PW/MCM-41 | CH2Cl2 | 12 | 10 |
12 | 50 wt% PW/MCM-41 | CH3OH | 12 | trace |
13 | 50 wt% PW/MCM-41 | THF | 12 | 79 |
14 | 50 wt% PW/MCM-41 | Et2O | 12 | 76 |
15 | 50 wt% PW/MCM-41 | toluene | 12 | - |
16 | 50 wt% PW/MCM-41 | AcOEt | 12 | - |
17 c | 50 wt% PW/MCM-41 | THF | 12 | 82 |
18 d | 50 wt% PW/MCM-41 | THF | 12 | 86 |
19 | 50 wt% PW/MCM-41 | THF | 6 | 56 |
20 | 50 wt% PW/MCM-41 | THF | 24 | 87 |