路径 | 双(频哪醇合)二硼(eq) | 温度/℃ | 时间/h | 底物(邻溴硝基苯)/% | HPLC收率/% |
1 | 1.0 | 80 | 25 | 9.4 | 38.9 |
2 | 1.1 | 80 | 22 | 5.9 | 49.4 |
3 | 1.2 | 80 | 23 | 2.3 | 53.2 |
4 | 1.3 | 80 | 24 | <0.1 | 67.3 |
5 | 1.3 | 70 | 50 | <0.1 | 66.7 |
6 | 1.3 | 80 | 26 | <0.1 | 67.5 |
7 | 1.3 | 90 | 20 | <0.1 | 71.2 |
8 | 1.3 | 100 | 20 | <0.1 | 81.8 |
9 | 1.3 | 100 | 2 | <0.1 | 72.0 |
10 | 1.3 | 100 | 3 | <0.1 | 81.9 |
11 | 1.3 | 100 | 4 | <0.1 | 83.5 |
12 | 1.3 | 100 | 5 | <0.1 | 80.6 |