序号

基元反应式

A (cm, mole, s)

β

E (calories/mole)

1

${\text{H}}_{\text{2}}+{\text{O}}_{\text{2}}=\text{2OH}$

1.70E+13

0.00

47780

2

$\text{OH}+{\text{H}}_{\text{2}}={\text{H}}_{\text{2}}\text{O}+\text{H}$

1.17E+09

1.3

3626

3

$\text{H}+{\text{O}}_{\text{2}}=\text{OH}+\text{O}$

5.13E+16

−0.816

16507

4

$\text{O}+{\text{H}}_{\text{2}}=\text{OH}+\text{H}$

1.80E+10

1.00

8826

5

$\text{H}+{\text{O}}_{\text{2}}+\text{M}={\text{HO}}_{\text{2}}+\text{M}$ ^a

2.10E+18

−1.00

0.00

6

$\text{H}+{\text{O}}_{\text{2}}+{\text{O}}_{\text{2}}={\text{HO}}_{\text{2}}+{\text{O}}_{\text{2}}$

6.70E+19

−1.42

0.00

7

$\text{H}+{\text{O}}_{\text{2}}+{\text{N}}_{\text{2}}={\text{HO}}_{\text{2}}+{\text{N}}_{\text{2}}$

6.70E+19

−1.42

0.00

8

$\text{OH}+{\text{HO}}_{\text{2}}={\text{H}}_{\text{2}}\text{O}+{\text{O}}_{\text{2}}$

5.00E+13

0.00

1000

9

$\text{H}+{\text{HO}}_{\text{2}}=\text{2OH}$

2.5E+14

0.00

1900

10

$\text{O}+{\text{HO}}_{\text{2}}={\text{O}}_{\text{2}}+\text{OH}$

4.80E+13

0.00

1000

11

$\text{2OH}=\text{O}+{\text{H}}_{\text{2}}\text{O}$

6.00E+08

1.30

0.00

12

${\text{H}}_{\text{2}}+\text{M}=\text{H}+\text{H}+\text{M}$ ^b

2.23E+12

0.50

92600

13

${\text{O}}_{\text{2}}+\text{M}=\text{O}+\text{O}+\text{M}$

1.85E+11

0.50

95560

14

$\text{H}+\text{OH}+\text{M}={\text{H}}_{\text{2}}\text{O}+\text{M}$ ^c

7.5E+23

−2.60

0.00

15

$\text{H}+{\text{HO}}_{\text{2}}={\text{H}}_{\text{2}}+{\text{O}}_{\text{2}}$

2.5E+13

0.00

700

16

${\text{HO}}_{\text{2}}+{\text{HO}}_{\text{2}}={\text{H}}_{\text{2}}{\text{O}}_{\text{2}}+{\text{O}}_{\text{2}}$

2.00E+12

0.00

0.00

17

${\text{H}}_{\text{2}}{\text{O}}_{\text{2}}+\text{M}=\text{OH}+\text{OH}+\text{M}$

1.30E+17

0.00

45500

18

${\text{H}}_{\text{2}}{\text{O}}_{\text{2}}+\text{H}={\text{HO}}_{\text{2}}+{\text{H}}_{\text{2}}$

1.60E+12

0.00

3800

19

${\text{H}}_{\text{2}}{\text{O}}_{\text{2}}+\text{OH}={\text{H}}_{\text{2}}\text{O}+{\text{HO}}_{\text{2}}$

1.00E+13

0.00

1800