方程

参数

数值(t = 25˚C)

作者

年份

${\text{I}}^{-}+{\text{H}}_2{\text{O}}_2\to {\text{IO}}^{-}+{\text{H}}_2\text{O}$

$k_1$

0.012 L/mol∙s

H. A. Liebhafsky

1932

${\text{IO}}^{-}+{\text{H}}_2{\text{O}}_2\to {\text{I}}^{-}+{\text{O}}_2+{\text{H}}_2\text{O}$

$k_5$

(6.6 ± 2.0) × 10⁷ L/mol∙s

H. Shiraishi

1992

$\text{HOI}+{\text{H}}_2{\text{O}}_2\to {\text{H}}^{+}+{\text{I}}^{-}+{\text{O}}_2+{\text{H}}_2\text{O}$

$k_6$

37 L/mol∙s

H. A. Liebhafsky

1932

${\text{I}}_2+{\text{H}}_2\text{O}\rightleftharpoons \text{HOI}+{\text{I}}^{-}$

$K_1$

4.77 × 10⁻¹³

D. A. Palmer

1985

$\text{HIO}\rightleftharpoons {\text{IO}}^{-}+{\text{H}}^{+}$

$K_2$

2.31 × 10⁻¹¹

M. Eigen

1962

$a=\frac{K_1\times K_2\times k_5}{k_1}$

a

(6.05 ± 1.83) × 10⁻¹⁴

C. F. Weber

1992

$b=\frac{K_1\times k_6}{k_1}$

b

1.47 × 10⁻⁹

C. F. Weber

1992