Complexes

H_dc kOe

U_eff/cm⁻¹

τ₀/s

Ref.

单核

Li(DME)₃[Nd(L¹)₂]

1

14.6

5.5 × 10⁻⁵

[18]

[(η₈-C₈H₈)Nd(η₉-C₉H₉)]

-

-

-

[26]

[Nd^III(TTA)₃(MeOH)₂]·0.5Azo-py

1

13.68

3.7 × 10⁻⁷

[27]

[Nd^III(TTA)₃(MeOH)₂]·0.5Azo-py (heated)

1

18.96

8.5 × 10⁻⁸

[27]

${\text{Cp}}_2^{*}\text{Nd}\left({\text{BPh}}_{\text{4}}\right)$

1

29

1.4 × 10⁻⁶

[28]

[Nd^III(NO₃)₃(18-crown-6)]

1

23.2

1.6 × 10⁻⁹

[29]

[Nd^III(NO₃)₃(1,10-diaza-18-crown-6)]

1

50.7

1.4 × 10⁻¹⁰

[29]

(n-Bu₄N)[Nd(HL²)₄(DMSO)]·nH₂O

1

24

1.0 × 10⁻⁴

[30]

(n-Bu₄N)[Nd(HFppa)₄(DMSO)]·nH₂O

1

7

9.5 × 10⁻⁷

[30]

[Nd(L³)₃] (1)

0.1

2.8

4.2 × 10⁻⁵

[31]

{[Nd(L⁴)₃(H₂O)₂]·2CH₃CN}_n (2)

2

19

4.1 × 10⁻⁷

[32]

{[Nd(L⁵)₂(CH₃COO)(H₂O)₂]}_n (3)

3.5

20

3.1 × 10⁻⁷

[32]

[NdL⁶(NO₃)₂]PF₆·MeCN (4)

1

23.6

1.1 × 10⁻⁸

[33]

[L⁶Nd(H₂O)₅] [I]₃·L⁷·(H₂O) (5)

2

27.23

8.98 × 10⁻⁷

[34]

{[Nd(ant)_1.5(DMF)₂]·(DMF)}_n (6)

1

22.9

1.57 × 10⁻⁷

[35]

{[Nd^III(pzdo)(H₂O)₄] [Co^III(CN)₆]}·0.5(pzdo)·4H₂O (7)

1

35.56

4.5 × 10⁻⁸

[36]

(NH₂Me₂)₃{[Nd(Mo₄O₁₃)(DMF)₄]₃(BTC)₂}∙8DMF (8)

0.5

23.65

4.69 × 10⁻⁸

[37]

[Nd(ntfa)₃(EtOH)₂] (9)

-

-

-

[38]

[Nd(ntfa)₃(phen)] (10)

1.5

18

2.2 × 10⁻⁷

[38]

[Nd(ntfa)₃(bipy)] (11)

1.5

31

1.0 × 10⁻⁹

[38]

[Nd(ntfa)₃(5,5’-Me₂bipy)] (12)

-

-

-

[38]

[Nd(ntfa)₃(4,4-Mt₂bipy)] (13)

1.5

19

8.7 × 10⁻⁸

[38]

[Nd^III(H₂O)₃] [Ag(CN)₂]₃ (14)

2

13.06

3.6 × 10⁻⁶

[39]

[Nd^III(H₂O)₃] [Au(CN)₂]₃ (15)

2

17.71

7.22 × 10⁻⁷

[39]

二核

{[Nd₂(2,5-pzdc)₃(H₂O)₄]·6H₂O}_n

2

35.4

2.5 × 10⁻⁸

[40]

{[Nd₂(CNCH₂COO)₆(H₂O)₄]·2H₂O}_n (18)

-

-

-

[41]

[Nd₂(μ₃-9-AC)₄(9-AC)₂(bpy)₂] (19)

2

8.0

7.5 × 10⁻⁶

[42]

三核

[Nd₃Cl₆(L⁸)₃(O)₂]Cl (20)

-

-

-

[43]

[Nd₃(dbm)₆(H₂L⁹)₃]⋅3CH₃OH

[44]

[Nd₃(mptbc)₄]Cl·solv

[45]

多核

${\left[\text{Nd}{\left({\text{W}}_{\text{5}}{\text{O}}_{\text{18}}\right)}_{\text{2}}\right]}_9^{-}$

1

51.4

3.55 × 10⁻¹⁰

[46]

$\left[{\text{Nd}}_6^{\text{III}}{\left({\mu }_{\text{3}}\text{-OH}\right)}_{\text{2}}{\left({\text{L}}^{\text{1}0}\right)}_{\text{4}}{\left({\text{L}}^{\text{1}0}\text{H}\right)}_{\text{2}}{\left(\text{DMF}\right)}_{\text{2}}{\left({\text{H}}_{\text{2}}\text{O}\right)}_{\text{5}}\right]$ (21)

-

-

-

[47]

$\left[{\text{Nd}}_6^{\text{III}}\left({\mu }_{\text{3}}\text{-OH}\right){\left({\mu }_{\text{3}}\text{-}{\eta }_{\text{2}}\text{-Form}\right)}_{\text{6}}{\left(\text{Form}\right)}_{\text{2}}{\left({\text{NO}}_{\text{3}}\right)}_{\text{2}}{\left(\text{BMPC}\right)}_{\text{3}}{\left({\text{H}}_{\text{2}}\text{O}\right)}_{\text{2}}\right]$ (22)

3

2.36

3.1 × 10⁻⁴

[48]

L¹ = bis(trimethylsilyl)cyclooctatetraenyl dianion; L² = N-(4-chlorophenyl)oxamic acid; HFppa = N-(4-fluorophenyl) oxamicacid; L³ = trispyrazolylborate; L⁴ = (N¹E, N²E)-N¹, N²-bis([2, 2’-bipyridin]-6-ylmethylene)ethane-1, 2-diamine; L⁵ = 2, 4-dinitrobenzoic acids; L⁶ = 3,5--dinitrobenzoic acids; H₂ant = 9, 10-anthracene-dicarboxylic acid; BMPC = (9E) -N’-(1-(6-((E)-1-(5-(pyridine-2-yl)-1H-pyrazole-3-carboylimino)ethyl)pyridin-2-yl)-ethenamine)-3-(pyridine-2-yl)-1H-pyrazole-5-carbohydrazide; BTC = 1,3,5-benzenetricarboxylate; L⁷ = ^tBuPO(NHⁱPr)₂; L⁸ = N’-(2-carboxide-imidazole) -[(2-hydroxy-3-methoxyphenyl)methylene]hydrazide; L⁹ = bis(2-pyridinal)ethylenediamine; bpy = 2,2’-bipyridine; 2, 5-pzdc = 2, 5-pyrazinedicarboxylate dianion; pzdo = pyrazine-N,N’-dioxide; Htta = thenoyl(trifluoro)acetone; Azo-py = 4,40-azopyridine; ntfa = 4, 4, 4-trifluoro-1-(naphthalen-2-yl)butane-1, 3-dionate; phen = phenanthroline; Cp^* = pentamethylcyclopentadienyl anione; bipy = 2, 2’-dipyridine; 5, 5’-Mesbipy = 5, 50-dimethyl-2, 20-dipyridine; H₃L¹⁰ = N’-(2-hydroxybenzylidene)-3-(pyridin-2-yl)-1H-pyrazole-5-carbohydrazid.