催化剂组成

反应温度/℃

原料组成

催化剂质量/g

丙烷转化率/%

丙烯选择性/%

文献

Cr₂O₃/SiO₂

550

C₃H₈:CO₂ = 1:7

0.5

29.7

80.5

[29]

yCrO_x/silicalite-1(y = 3)

550

C₃H₈:CO₂:Ar = 4:20:1

0.5

45

65

[28]

Ga₂O₃/TiO₂

600

C₃H₈:CO₂:N₂ = 1:2:15

0.2

9

-

[34]

Ga₂O₃/Al₂O₃

600

C₃H₈:CO₂:N₂ = 1:2:15

0.2

23

-

[34]

Ga₂O₃/ZrO₂

600

C₃H₈:CO₂:N₂ = 1:2:15

0.2

18

-

[34]

Ga₂O₃/Al₂O₃

550

C₃H₈:CO₂:N₂ = 1:3:27

0.15

35.35

95

[35]

Ga₂O₃/SiO₂

600

C₃H₈:CO₂:N₂ = 1:3:10

1

30~45

90-92

[36]

Rh/Al₂O₃

550

C₃H₈:CO₂ = 1:3

0.3

7

25

[37]

5%Ru/CeO₂

550

C₃H₈:CO₂:Ar = 1:2:5

0.25

3.7 (m²/g)

-

[38]

5%Ru/ZrO₂

550

C₃H₈:CO₂:Ar = 1:2:5

0.25

2.5 (m²/g)

-

[38]

CeZrAlO_x

500

C₃H₈:CO₂:He = 4:4:3

0.2

3

82

[39]

5%Pd/CeZrAlO_x

500

C₃H₈:CO₂:He = 4:4:3

0.2

3.3

76

[39]

5%Pd/CeZrO_x

500

C₃H₈:CO₂:He = 4:4:3

0.2

10.1

92

[39]

0.05%Pt/Al₂O₃

575

-

0.1

5

95

[40]

5%Pt/Al₂O₃

575

-

0.1

27

62

[40]

Fe₃Ni/CeO₂

550

C₃H₈:CO₂:Ar = 1:1:2

0.1

2.7

58.2

[41]

Fe₃Pt/CeO₂

550

C₃H₈:CO2:Ar = 1:1:2

0.1

1.1

32

[41]

Ni₃Pt/CeO₂

550

C₃H₈:CO₂:Ar = 1:1:2

0.1

11.6

2.8

[41]

Pt1Fe5/S-1

550

C₃H₈:CO₂:N₂ = 1:1:6

0.15

43

92

[42]

PtCo/SiBeta

550

C₃H₈:CO₂:N₂ = 1:1:3

0.1

51.8

92

[43]

0.1 wt%Pt/1.0 wt%Sn/CeO₂

550

-

0.15

15.1

63.9

[44]

1Pt/1Sn-CeO₂

550

C₃H₈:CO₂:Ar = 1:2:4

1

64

18

[45]

1Pt/CeO₂

500

C₃H₈:CO₂:N₂ = 4:1:20

0.5

42

19

[46]

1Pt7Sn/CeO₂

500

C₃H₈:CO₂:N₂ = 4:1:20

0.5

18

80

[46]

PtSn/SiO₂

550

C₃H₈:CO₂ = 1:1

0.2

50

93

[47]

PtSn3/SiO₂

550

C₃H₈:CO₂ = 1:1

0.2

47

96

[47]

Pt-Co-In/CeO₂

550

C₃H₈:CO₂:He = 1:1:2

0.2

47~52

95~99

[12]