序号

化学反应

正向反应速率系数

逆向反应速率系数

A_1f

A_2f

A_3f

A_1b

A_2b

A_3b

1

${\text{O}}_2+{\text{I}}_1\rightleftharpoons 2\text{O}+{\text{I}}_1$

3.61E18

59,400

−1

3.01E15

0

−0.5

2

${\text{N}}_2+{\text{I}}_2\rightleftharpoons 2\text{N}+{\text{I}}_2$

1.92E17

113,100

−0.5

1.09E16

0

−1.5

3

${\text{N}}_2+\text{N}\rightleftharpoons 2\text{N}+\text{N}$

4.15E22

113,100

−1.5

2.32E21

0

−1.5

4

$\text{NO}+{\text{I}}_3\rightleftharpoons \text{N}+\text{O}+{\text{I}}_3$

3.97E20

75,600

−1.5

1.01E20

0

−1.5

5

$\text{NO}+\text{O}\rightleftharpoons {\text{O}}_2+\text{N}$

3.18E9

19,700

1

9.63E11

3600

0.5

6

${\text{N}}_2+\text{O}\rightleftharpoons \text{NO}+\text{O}$

6.75E13

37,500

0

1.50E13

0

0

7

$\text{N}+\text{O}\rightleftharpoons {\text{NO}}^{+}+{\text{e}}^{-}$

9.03E9

32,400

0.5

1.80E19

0

−1.0

8

$\text{O}+{\text{e}}^{-}\rightleftharpoons {\text{O}}^{+}+{\text{e}}^{-}+{\text{e}}^{-}$

3.60E31

158,000

−2.91

2.20E20

0

−4.5

9

$\text{N}+{\text{e}}^{-}\rightleftharpoons {\text{N}}^{+}+{\text{e}}^{-}+{\text{e}}^{-}$

1.10E32

169,000

−3.14

2.20E20

0

−4.5

10

$\text{O}+\text{O}\rightleftharpoons {\text{O}}_2^{+}+{\text{e}}^{-}$

1.60E17

80,800

−0.98

8.02E21

0

−1.5

11

$\text{O}+{\text{O}}_2^{+}\rightleftharpoons {\text{O}}_2+{\text{O}}^{+}$

2.92E18

28,000

−1.11

7.80E11

0

0.5

12

${\text{N}}_2+{\text{N}}^{+}\rightleftharpoons \text{N}+{\text{N}}_2^{+}$

2.02E11

13,000

0.81

7.80E11

0

0.5

13

$\text{N}+\text{N}\rightleftharpoons {\text{N}}_2^{+}+{\text{e}}^{-}$

1.40E13

67,800

0

1.50E22

0

−1.5

14

${\text{O}}_2+{\text{N}}_2\rightleftharpoons \text{NO}+\text{NO}+{\text{e}}^{-}$

1.38E20

141,000

−1.84

1.00E24

0

−2.5

15

$\text{NO}+{\text{I}}_4\rightleftharpoons {\text{NO}}^{+}+{\text{e}}^{-}+{\text{I}}_4$

2.20E15

108,000

−0.35

2.20E26

0

−2.5

16

$\text{O}+{\text{NO}}^{+}\rightleftharpoons \text{NO}+{\text{O}}^{+}$

3.63E15

50,800

−0.6

1.50E13

0

0.0

17

${\text{N}}_2+{\text{O}}^{+}\rightleftharpoons \text{O}+{\text{N}}_2^{+}$

3.40E19

23,000

−2.0

2.48E19

0

−2.2

18

$\text{N}+{\text{NO}}^{+}\rightleftharpoons \text{NO}+{\text{N}}^{+}$

1.00E19

61,000

−0.93

4.80E14

0

0.0

19

${\text{O}}_2+{\text{NO}}^{+}\rightleftharpoons \text{NO}+{\text{O}}_2^{+}$

1.80E15

33,000

0.17

1.80E13

0

0.5

20

$\text{O}+{\text{NO}}^{+}\rightleftharpoons {\text{O}}_2+{\text{N}}^{+}$

1.34E13

77,270

0.31

1.00E14

0

0.0