Complexes

Binding mode

R_X−Y/nm

∠FXY/˚

ΔR_F−X/nm

ΔE/kJ∙mol⁻¹

1 (H₃GeF + benzene)

I

0.3237

177.0

0.0011

−17.38

2 (H₃GeF + pyridine)

I

0.3313

178.8

0.0007

−13.81

3 (H₃GeF + pyridine)

II

0.2465

179.1

0.0041

−34.19

4 (H₃GeF + pyrrole)

I

0.3131

174.4

0.0016

−21.86

5 (H₃GeF + furan)

I

0.3216

172.2

0.0011

−16.61

6 (H₃GeF + furan)

II

0.2914

175.2

0.0010

−15.17

7 (H₃GeF + thiophene)

I

0.3198

172.4

0.0011

−17.96

8 (H₃GeF + thiophene)

II

0.3375

172.8

0.0010

−16.35

9 (H₃SiF + benzene)

I

0.3280

177.3

0.0006

−15.50

10 (H₃SiF + pyridine)

I

0.3347

179.1

0.0003

−12.80

11 (H₃SiF + pyridine)

II

0.2367

179.2

0.0035

−34.09

12 (H₃SiF + pyrrole)

I

0.3179

174.7

0.0010

−19.44

13 (H₃SiF + furan)

I

0.3258

172.3

0.0006

−15.30

14 (H₃SiF + furan)

II

0.2939

175.9

0.0005

−14.08

15 (H₃SiF + thiophene)

I

0.3240

172.2

0.0006

−16.22

16 (H₃SiF + thiophene)

II

0.3387

173.3

0.0006

−14.64