配合物

Hdc/kOe

Ueff/K

τ0/s

v/mT/s

TB/K

Ref.

[Tb2CoIII2(OMe)2(teaH)2(O2CPh)4(MeOH)4] (2)

1

14.3

2.84 × 10−6

[13]

[Dy2CoIII2(OMe)2(teaH)2(O2CPh)4(MeOH)4] (3)

0

88.8(2)

5.64×10−8

[14]

[Dy2CoIII2(OMe)2(dea)2(O2CPh)4(MeOH)4] (4)

0

102.9

6.05 × 10−8

[14]

[Dy2CoIII2(OMe)2(mdea)2(O2CPh)4(NO3)2] (5)

0

78.6

1.03 × 10−7

[14]

[Dy2CoIII2(OMe)2(bdea)2(O2CPh)4(MeOH)4] (6)

0

114.4

3.38 × 10−8

[14]

[Dy2CoIII2(OMe)2(teaH)2(acac)4(NO3)2] (7)

0

27

8.1 × 10−6

[15]

[Dy2CoIII2(OH)2(teaH)2(acac)4(NO3)2]∙4H2O (8)

0

28

7.4 × 10−6

[15]

[Dy2CoIII2(OMe)2(mdea)2(acac)4(NO3)2] (9)

0

38

2.6 × 10−6

[15]

[CoIII2Dy2(OMe)2(O2CPh-2-Cl)4(bdea)2(NO3)2] (10)

0

114.4

1.8 × 10−8

[16]

[CoIII2Dy2(OMe)2(O2CPh-4-tBu)4(bdea)2(NO3) (MeOH)3] (11)

0

110.1

137.3

3.8 × 10−9

5.6 × 10−8

[16]

[CoIII2CoIIDy(OH)(O2CPh-4-OH)(bdea)3(NO3)3 (MeOH)] (12)

1.5

167.3

3.4 × 10−7

[16]

[CoIII2Dy2(OMe)2(O2CPh-2-CF3)4(bdea)2(NO3)2] (13)

0

125.8

1.4 × 10−8

[16]

[CoIII2Dy2(mdea)4(hfacac)3(O2CCF3)(H2O)]

0

32.9

1.4 × 10−6

[16]

[CoIII2Dy2(μ3-OH)2(o-tol)4(mdea)2(NO3)2] (14)

0

116.9(2)

9.8 × 10−9

[17]

[CoIII2Tb2(μ3-OH)2(o-tol)4(mdea)2(NO3)2]

5

49.2

6.6 × 10−11

[17]

[Co2Dy2(L1)4(NO3)2(THF)2]∙4THF (15)

0

15.7

117.4

7.7 × 10−4

6.2 × 10−7

235

3

[18]

[Dy2Co2(L2)4(NO3)2(DMF)2]∙2DMF (16)

0

125.1

2.67 × 10−6

[19]

[L32CoII2GdIII][NO3] (17)

0

27.2

1.7 × 10−7

[20]

[Dy2CoII(C7H5O2)8] (18)

0

16.77(4)

127.27(2)

3.55 × 10−5

1.69 × 10−9

[21]

[CoII2Dy(TTTTCl)2(MeOH)]NO3∙3MeOH (20)

0

401(13)

1.3(6) × 10−10

[22]

[CoII2Dy(TTTTCl)2(MeOH)][CoIII(HTTTTCl)] (NO3)2∙2.5MeOH∙2H2O (21)

0

536(10)

3.8(10) × 10−11

20

10

[22]

[Co2Dy2(L4)2(pdm)2(CH3COO)2(CH3OH)2] (NO3)2∙xCH3OH∙yH2O (22)

0

64.6(1)

1.3(7) × 10−6

[23]

[Co2Dy10(L5)4(OAc)16(SCN)2(MeCN)2(H2O)4(OH)2 (μ3-OH)4]∙2Co(SCN)4H2O∙2MeCN∙2H2O (24)

0

4.3

25

1.13 × 10−4

3.14 × 10−6

[24]

[CoDy3(HBpz3)6(dto)3]∙4CH3CN∙2CH2Cl2 (25)

0.8

52

3.6 × 10−8

[25]

[Co4Ln2(μ3-O)2(μ-N3)2(OH)2(H2O)2(HL6)4] (26)

0

73.51

1.68 × 10−8

[26]

[CoIII2Dy4(OH)2(ib)8(bdea)2(NO3)4(H2O)2]∙2MeCN

0

26.6

2.26 × 10−5

[27]

[CoIII3Dy3(µ3-OH)4(O2CtBu)6(teaH)3]∙(NO3)2∙H2O

2

17.5

2.3×10−6

[28]

[Dy2Co2(2, 3-DCB)10(2, 2’-bpy)2]

2

2

7 × 10−5

[29]

[Dy2Co8(μ3-OCH3)2(L7)4(HL7)2(OAc)2(NO3)2(CH3CN)2]

0

14.89

1.68 × 10−7

[30]

[Dy4Co6(L7)4(HL)2(OAc)6(OCH2CH2OH)2 (HOCH2CH2OH)(H2O)]

0

5.49

2.88 × 10−5

[30]

[Dy(4-MMNO)(H2O)5][Co(CN)6]

0

595(3)

1.29 × 10−11

50

20

[31]

[Dy2Co4(L8)4(NO3)2(OH)4(C2H5OH)2]∙2C2H5OH

0

27.50

3.36 × 10−8

[32]

[CoII4Dy4(L9)4(μ1,3-Piv)4(μ1,1,3-Piv)2(η1-Piv)2(μ3-OH)4 (MeOH)2]∙3MeOH∙H2O

0

12.5

1.51 × 10−6

[33]

[CoIIIDy(CH3CN)0.5(L10)3(NO3)3]

3

2.58

3.11 × 10−5

[34]

[CoIII2Dy4(μ3-OH)2(NO3)4(OAc)4(L11)4(DMF)2]∙2C2H5OH

0

27.8

1.94 × 10−7

[35]

[DyCo(CN)6(H2L12)(H2O)(DMF)]2∙5H2O

1

11.17

1.36 × 10−6

[36]

[CoIII2Dy3Na(CH3CH2COO)6(OH)6(NO3)4(H2O)2]

0

60.3

9.6 × 10−8

[37]

[Dy18CoIICoIII6(OH)14(CO3)9(CH3CH2COO)6(dea)12(H2O)30]

0

3.53

6.03 × 10−6

[38]

(PPh4)[Dy2(bbpen)2(Co(CN)6)]∙3.5MeCN

0

659(10)

20

15

[39]

2

982(14)

[Ni(L13)Dy(H2O)4][Co(CN)6]∙3H2O

0.8

47.02

6.7 × 10−9

[40]

[Dy(pyzic){Dy3Co2(pyzha)6(*pyzha)(NO3)2(H2O) (MeOH)2}]2

0

1.46

2.4 × 10−5

[41]

Dy[CoIII(CN)6]

2

58.3(5)

1.76(13) × 10−6

[42]

[(L14)4Ru2Co2](BF4)4

3

12.58

3.1 × 10−5

[43]

[Nd(18-crown-6)(H2O)4][Co(CN)6]∙2H2O

0.8

37.0

2.9×10−8

[44]

[CoIII4Dy3(L15)4(μ4-O)2(μ-OMe)2(μ1,3-OAc)4(H2O)2(NO3)2]·NO3∙3CH3OH∙1.5H2O

0

73.5

34.7

9.40 × 10−7

6.91 × 10−7

[45]

[CoII4Gd(OH)2(chp)4(saloh)5(H2O)(MeCN)(Solv)]

2

86

6.95 × 10−12

[46]

[CoII4Dy(OH)2(chp)4(saloh)5(H2O)(MeCN)(Solv)]

2

66

3.43× 10−7

[46]

[CoIIDy (R-HL16)(hfac)5]

1.5

297.4

88.66

4.7 × 10−10

4.7 × 10−6

[47]

[Co2Eu(NO3)(Piv)6(EtPy)2]

1

4

4.7 × 10−6

[48]

[L17CoGdCoL17]NO3

0

29.5

1.3 × 10−7

[49]

[L17CoYCoL17]NO3∙CH3OH

2

51.3

2 × 10−6

[49]

[L17CoGdCoL17]ClO4∙2CHCl3

0

29.4

1.47 × 10−7

[49]

[L17CoGdCoL17](C5HF6O2)

1

27.4

1.50 × 10−7

[49]

Co(μ-L18)(μ-CCl3COO)Y(NO3)2]

1.2

8.4(6)

3.2(4) × 10−6

[50]

[Co(μ-L18)(μ-CH3COO)Y(NO3)2]∙CH3CN

1.2

11.0(4)

2.5(2) × 10−6

[50]

[Co(μ-L18)(μ-PhCOO)Y(NO3)2]∙3CH3CN∙2H2O

1.2

13.7(8)

2.6(4) × 10−6

[50]

[Co(μ-L18)-(μ-tBuCOO)Y(NO3)2]∙CHCl3∙2H2O

1.2

18.7(6)

7.4(9) × 10−7

[50]

Hib = isobutyric acid; 2, 3-HDCB = 2, 3-dichlorobenzoic acid; 2,2’-bpy = 2,2’-bipyridine; H3L7 = 3-amino-1,2-propanediol with 2-hydroxy-1-naphthaldehyde; 4-MMNO = 4-methylmorpholine N-oxide; H2L8 = 2-(((2-hydroxy-3-methoxybenzyl) imino)methyl)-4-methoxyphenol; H2L9 = 2-((2-hydroxy-3-methoxybenzylidene)amino)benzoic acid; Piv = (μ-OH2)(O2CCMe3)4(HO2CCMe3)4; HL10 = 8-hydroxyquinoline; H2L11 = (E)-1-(((2-(hydroxymethyl)phenyl)imino)methyl)nap-hthalen-2-ol; H2L12 = 2,6-diylbis(ethan-1-yl-1-ylidene)-di(isonicotinohydrazide); H2dea = diethanolamine; H2bbpen = N, N’-bis(2-hydroxybenzyl)-N, N’-bis(2-picolyl)ethylene diamine); H2L13 = N, N-ethylenebis(3-methoxysalicylaldiimine); H2pyzha = pyrazinehydroxamic acid; Hpyzic = pyrazinic acid; HL14 = bis(tridentate) pyrazolate-bridged ligand; H2L15 = 3-methoxysalicyl-aldehyde with 2-amino-2-methyl-1-propanol; Hchp = deprotonated 6-chloro-2-hydroxypyridine; H2saloh = 3,5-ditert-butylsalicylic acid; HL16 = chiral nitronyl-nitroxide ligands; EtPy = 2-ethynylpyridine; H3L17 = 2-hydroxy3-methoxybenzaldehyde (o-vanillin) with N, N’, N’’-trimethylphosphorothioictrihydrazide, P(S)[NMe-NH2]3; H2L18 = Fe[(C5H4){-C(Me)=N−N=CH-C6H3-2-OH-3-OCH3}]2