催化剂组合 编号

催化剂组合

温度

乙醇转化率(%)

乙烯选择性(%)

C4烯烃选择性(%)

乙醛选择性(%)

碳数为4-12脂肪醇选择性(%)

甲基苯甲醛和甲基苯甲醇选择性(%)

其他生成物的选择性(%)

A1

200 mg 1 wt% Co/SiO₂-200 mg HAP-乙醇浓度1.68 ml/min

250

2.07

1.17

34.05

2.41

52.59

0

9.78

275

5.85

1.63

37.43

1.42

53.21

0

6.31

300

14.97

3.02

46.94

4.71

35.16

1

9.17

325

19.68

7.97

49.7

14.69

15.16

2.13

10.35

350

36.80

12.46

47.21

18.66

9.22

1.69

10.76

A2

200 mg 2 wt% Co/SiO₂-200 mg HAP-乙醇浓度1.68 ml/min

250

4.60

0.61

18.07

0.94

72.99

0

7.39

275

17.20

0.51

17.28

1.43

72.62

0

8.16

300

38.92

0.85

19.6

2.21

67.5

0

9.84

325

56.38

1.43

30.62

3.79

51.21

0

12.95

350

67.88

2.76

39.1

4.2

36.92

1.87

15.15

A3

200 mg 1 wt% Co/SiO₂-200 mg HAP-乙醇浓度0.9 ml/min

250

9.7

0.13

5.5

1.23

85.09

3.97

4.08

275

19.2

0.33

8.04

1.71

82.07

2.88

4.97

300

29.3

0.71

17.01

3.63

66.9

3.18

8.57

325

37.6

1.83

28.72

5.72

49.77

3.44

10.52

350

48.9

2.85

36.85

7.23

38.29

3.51

11.27

400

83.7

6.76

53.43

8.95

14.37

3.38

13.11

450

86.4

14.84

49.9

8.39

12.41

2.09

12.37

A4

200 mg 0.5 wt% Co/SiO₂-200 mg HAP-乙醇浓度1.68 ml/min

250

4.0

0.27

9.62

1.49

79.51

6.53

2.58

275

12.1

0.36

8.62

1.66

81.44

5.18

2.74

300

29.5

0.54

10.72

2.41

76.32

5.88

4.13

325

43.3

1.02

18.89

4.42

59.65

7.64

8.38

350

60.5

2.23

27.25

6.8

45

8.73

9.99

400

88.4

3.67

41.02

10.82

16.47

10.51

17.51

A5

200 mg 2 wt% Co/SiO₂-200 mg HAP-乙醇浓度0.3 ml/min

250

14.8

0.14

1.96

3.27

88.42

3.36

2.85

275

12.4

0.19

6.65

11.27

70.05

5.77

6.07

300

20.8

0.74

10.12

13.18

62.45

5.66

7.85

325

28.3

1.14

13.86

15.83

56.28

2.92

9.97

350

36.8

3.11

18.75

16.16

48

4.36

9.62

400

76.0

6.38

38.23

9.64

25.72

3.71

16.32

A6

200 mg 5 wt% Co/SiO₂- 200 mg HAP-乙醇浓度1.68 ml/min

250

13.4

0.2

3.3

11.59

80.23

1.04

3.64

275

12.8

0.38

7.1

26.67

55.7

2.02

8.13

300

25.5

1.46

7.18

28.51

51.07

2.12

9.66

350

55.8

14.49

10.65

42.75

19.83

3.74

8.54

400

83.3

6.18

37.33

16.08

19.48

7.61

13.32

A7

50 mg 1 wt% Co/SiO₂- 50 mg HAP-乙醇浓度0.3 ml/min

250

19.7

0.18

5.75

3.69

87.26

0

3.12

275

29.0

0.31

6.56

3.27

84.43

0

5.43

300

40.0

0.57

8.84

3.98

79.99

0

6.62

350

58.6

2.28

18.64

8.23

45.04

3.24

22.57

400

76.0

8.31

33.25

5.79

24.57

6.76

21.32

A8

50 mg 1 wt% Co/SiO₂- 50 mg HAP-乙醇浓度0.9 ml/min

250

6.3

0.14

5.63

1.59

86.5

0

6.14

275

8.8

0.2

8.52

4.31

82.26

0

4.71

300

13.2

0.52

13.82

4.6

72.79

0

8.27

350

31.7

1.45

25.89

4.15

48.52

2.25

17.74

400

56.1

6.4

41.42

4.32

24.15

0

23.71

A9

50 mg 1 wt% Co/SiO₂- 50 mg HAP-乙醇浓度2.1 ml/min

250

2.1

0.16

5.4

4.99

81.93

0

7.52

275

3.0

0.33

9.68

4.66

75.09

0

10.24

300

4.7

0.53

16.1

5.08

61.02

1.57

15.7

350

13.4

2.84

31.04

3.75

39.29

2.09

20.99

400

40.8

6.36

42.04

4.71

27.07

0

19.82

A10

50 mg 5 wt% Co/SiO₂- 50 mg HAP-乙醇浓度2.1 ml/min

250

0.3

1.06

2.19

12.49

83.06

0

1.2

275

1.0

0.58

1.65

4.67

92.77

0

0.33

300

1.7

0.8

2.17

5.8

90.32

0

0.91

350

9.0

0.81

3.3

4.3

88.98

0.7

1.91

400

28.6

1.93

10.29

3.68

79.2

0

4.9

A11

50 mg 1 wt% Co/SiO₂ + 90 mg石英砂-乙醇浓度1.68 ml/min，无HAP

250

0.2

2.14

0.1

97.76

0

0

0

275

0.5

2.83

1

94.75

0

0

1.42

300

1.6

3.24

1.82

93.76

0

0

1.18

350

8.2

7.61

4.35

85.83

0

0

2.21

400

32.6

13.35

7.93

75.03

0

0

3.69

A12

50 mg 1 wt% Co/SiO₂- 50 mg HAP-乙醇浓度1.68 ml/min

250

1.4

0.14

6.17

3.48

81.43

7.45

1.33

275

3.5

0.18

8.11

4.2

80

5.3

2.21

300

6.9

0.43

11.22

8.83

71.28

5.34

2.9

350

19.9

1.17

22.26

13.48

46.5

5.66

10.93

400

44.5

3.63

36.3

16.25

25.79

5.32

12.71

A13

67 mg 1 wt% Co/SiO₂- 33 mg HAP-乙醇浓度1.68 ml/min

250

1.3

0.31

5.19

5.39

79.6

6.87

2.64

275

2.3

0.66

7.62

7.67

74.74

5.91

3.4

300

4.1

1.2

12.74

19.65

55.4

4.87

6.14

350

14.6

2.53

23.46

26.42

30.99

3.52

13.08

400

40.0

5.19

27.91

24.73

22.05

3.85

16.27

A14

33 mg 1 wt% Co/SiO₂- 67 mg HAP-乙醇浓度1.68 ml/min

250

2.5

0.14

1.89

2.63

90.74

3.18

1.42

275

5.3

0.14

2.55

2.8

89.7

2.85

1.96

300

10.2

0.25

3.61

4.07

85.12

3.43

3.52

350

24.0

1.04

10.83

6.25

70.1

4.59

7.19

400

53.6

2.92

22.3

7.22

49.31

7.48

10.77

B1

50 mg 1 wt% Co/SiO₂- 50 mg HAP-乙醇浓度1.68 ml/min

250

1.4

0.1

6.32

5.7

83.4

0

4.48

275

3.4

0.19

8.25

4.03

81.35

0

6.18

300

6.7

0.45

12.28

4.11

73.45

0

9.71

350

19.3

1.22

25.97

4.4

48.32

2.44

17.65

400

43.6

3.77

41.08

4.13

26.79

1.95

22.28

B2

100 mg 1 wt% Co/SiO₂- 100 mg HAP-乙醇浓度1.68 ml/min

250

2.8

0.2

3.26

2.78

89.53

0

4.23

275

4.4

0.32

4.97

3.92

83.2

0

7.59

300

6.2

0.72

9.32

5.21

71.37

3.09

10.29

350

16.2

2.11

22.88

6.07

47.39

4.74

16.81

400

45.1

8.1

38.7

7.12

24.22

4.34

17.52

B3

10 mg 1 wt% Co/SiO₂- 10 mg HAP-乙醇浓度1.68 ml/min

250

0.4

0.31

2.85

18.98

76.81

0

1.05

275

0.6

0.42

5.35

19.79

73.56

0

0.88

300

1.1

0.74

7.61

19.86

70.07

0

1.72

325

3.3

1.16

7.74

16.61

67.57

3.77

3.15

350

6.0

1.81

13.81

20.27

53.38

4.64

6.09

400

21.1

3.79

21.21

19.72

39.51

4.88

10.89

B4

25 mg 1 wt% Co/SiO₂- 25 mg HAP-乙醇浓度1.68 ml/min

250

0.5

0.1

6.62

6.91

82.18

4.19

0

275

1.1

0.32

6.62

2.93

83.06

1.93

5.14

300

3.0

0.31

5.05

8.47

78.11

4.04

4.02

325

6.1

0.69

8.33

12.29

70.48

3.89

4.32

350

9.6

0.76

13.1

14.26

59.75

3.89

8.24

400

33.5

2.68

21.45

15.15

43.12

5.21

12.39

B5

50 mg 1 wt% Co/SiO₂- 50 mg HAP-乙醇浓度2.1 ml/min

250

2.1

0.18

4.3

3.98

84.81

4.76

1.97

275

3.8

0.35

5.06

7.67

78.13

4.22

4.57

300

5.8

0.47

7.92

14.04

66.89

4.41

6.27

325

9.8

0.77

11.69

14.62

59.29

5.28

8.35

350

15.9

1.57

15.34

15.03

53.41

4.14

10.51

400

45.0

3.93

25.83

13.82

36.87

6.16

13.39

B6

75 mg 1 wt% Co/SiO₂- 75 mg HAP-乙醇浓度1.68 ml/min

250

2.8

0.23

4.5

1.97

85.16

4.87

3.27

275

7.5

0.15

4.79

2.16

86.83

3.82

2.25

300

12.6

0.5

8.77

4.81

74.9

5.05

5.97

325

15.9

1.04

16.06

7.44

57.98

6.75

10.73

350

27.0

0.99

22.41

9.95

48.26

4.44

13.95

400

63.2

4.11

30.48

11.12

34.9

4.71

14.68

B7

100 mg 1 wt% Co/SiO₂- 100 mg HAP-乙醇浓度0.9 ml/min

250

4.4

0.13

4.08

2.04

86.01

4.79

2.95

275

7.9

0.15

6.62

3.49

79.79

5.67

4.28

300

11.7

0.2

12.86

6.47

68.02

6.71

5.74

325

17.8

1.42

18.45

7.94

59.12

7.14

5.93

350

30.2

1.53

25.05

10.3

49.36

6.3

7.46

400

69.4

2.51

38.17

13.96

26.64

4.71

14.01