43	12.43	C₂₀H₂₂O₄	327.1596	+H	−1.8	107.048、175.071、160.052	licarinA
44	12.47	C₁₅H₁₀O₆	287.0556	+H	−0.5	137.059、153.018	木犀草素
45	12.71	C₁₅H₁₂O₆	289.0712	+H	−0.7	123.043、270.050	3,5-Dimethoxy-1,6-dihydroxyanthone
46	12.78	C₂₀H₂₄O₆	361.1651	+H	−2.9	137.059	(+)-isolariciresinol
47	12.83	C₁₇H₂₄O₅	331.1521	+Na	−1.1	137.058、219.100	乙酰大花旋覆花内酯
48	13.08	C₃₀H₃₄O₁₅	657.1795	+Na	−2.1	263.048	山奈素-7-O-鼠李糖苷
49	13.18	C₁₅H₁₀O₇	303.0505	+H	1.8	135.044、287.056	herbacetin
50	13.35	C₁₆H₁₂O₅	285.0763	+H	1.3	107.048、253.049	calycosin
51	13.48	C₂₀H₂₂O₆	359.1495	+H	−2.7	269.082、325.107	isobutylshikonin
52	13.51	C₂₁H₂₄O₇	389.1600	+H	−3.6	125.059、357.133	trachelogenin
53	13.63	C₂₁H₂₂O₇	387.1444	+H	−2.3	151.039、345.096	floranol
54	13.95	C₁₅H₁₀O₅	271.0606	+H	−6.0	167.033	大黄素
55	14.09	C₁₈H₂₀O₆	355.1158	+Na	5.8	148.050、151.075	3-duartin
56	14.19	C₁₅H₁₀O₆	287.0556	+H	1.3	229.049	3-羟基黄芩素
57	14.26	C₁₇H₁₄O₇	331.0818	+H	0.1	107.048、315.050	商陆素
58	14.32	C₁₇H₁₆O₇	333.0974	+H	1.3	151.039、167.034	1-羟基--四甲氧基黄酮
59	14.38	C₂₂H₂₄O₈	417.1549	+H	−0.6	385.128	1-acetoxypinoresinol
60	14.62	C₂₀H₁₈O₇	371.1131	+H	−2.8	149.023、181.049	sesamolin
61	14.64	C₂₀H₃₀O₅	351.2171	+H	−1.6	167.070、235.171	14-去氧-12-羟基穿心莲内酯
62	15.04	C₁₅H₁₀O₄	255.0657	+H	−8.2	107.048、151.038	1-羟基-3-甲氧基蒽醌
63	15.15	C₁₈H₃₄O₅	353.2304	+Na	−0.8	111.08	天师酸
64	15.35	C₂₀H₂₂O₅	343.1545	+H	−3.2	180.077	风藤素B
65	15.62	C₂₀H₁₈O₆	355.1182	+H	2.6	151.038	细辛脂素
66	15.64	C₁₇H₁₄O₆	315.0869	+H	−0.4	131.049、283.060	尼泊尔鸢尾异黄酮
67	16.32	C₄₈H₇₈O₁₈	943.5266	+H	−0.7	273.222、423.361	大豆皂苷І
68	16.85	C₂₀H₂₀O₆	357.1338	+H	−0.8	123.043	三白酯酮
69	17.67	C₂₈H₄₂O₁₁	577.2625	+Na	−0.4	93.056	11-methoxy-6-ylhexopyranoside
70	18.04	C₂₀H₁₆O₆	353.1025	+H	0.9	298.047	licoisoflavoneB
71	18.58	C₂₀H₁₆O₆	353.1025	+H	−1.7	213.055、297.039	sophora-iso-flavoneA
72	19.42	C₂₀H₁₆O₅	337.1076	+H	−1.3	283.06	猫尾草异黄酮
73	19.68	C₂₅H₂₆O₆	423.1808	+H	−3.9	177.018、311.054	6,8-diprenylorobol
74	20.02	C₁₅H₁₆O₃	262.1443	+NH₄	−4.9	213.055	蛇床子素
75	20.2	C₂₀H₂₂O₇	392.1709	+NH₄	−1.8	167.072	1-羟基松脂酚
76	20.43	C₄₂H₆₈O₁₂	787.4608	+Na	3.2	133.086	柴胡皂苷E
77	23.11	C₂₀H₃₄O₃	323.2586	+H	2.6	261.223	豨莶精醇
78	23.85	C₂₉H₄₆O	411.3627	+H	−3.3	107.049、175.111	4,22-二烯-3-酮豆甾烷
79	24.25	C₃₀H₄₈O	425.3783	+H	−2.4	121.100、135.116	羽扇豆烯酮
80	24.57	C₃₀H₄₆O₃	455.3525	+H	−2.9	439.322	(5xi,18xi)-3-oxolup-20-en-28-saure
81	24.64	C₂₉H₅₀O₄	463.3787	+H	−5.6	97.100	tocospiroA
82	25.19	C₃₀H₄₈O₂	441.3773	+H	−2.1	189.164、427.363	glochidonol