选点个数 | WHO对照品 | EP对照品 | ||
保留时间(min) | 分子量 | 保留时间(min) | 分子量 | |
1 | 12.571 | 18,000 | 12.605 | 16,285 |
2 | 12.779 | 15,600 | 12.842 | 14,480 |
3 | 13.046 | 13,600 | 13.208 | 12,509 |
4 | 13.304 | 12,000 | 13.600 | 10,634 |
5 | 13.829 | 9600 | 13.950 | 9407 |
6 | 14.139 | 8400 | 14.300 | 8020 |
7 | 14.629 | 7200 | 14.503 | 7533 |
8 | 14.888 | 6600 | 14.742 | 6956 |
9 | 15.154 | 6000 | 15.010 | 6228 |
10 | 15.454 | 5400 | 15.311 | 5502 |
11 | 15.771 | 4800 | 15.642 | 4811 |
12 | 16.121 | 4200 | 16.012 | 4209 |
13 | 16.496 | 3600 | 16.413 | 3403 |
14 | 16.913 | 3000 | 16.851 | 2912 |
15 | 17.371 | 2400 | 17.345 | 2409 |
16 | 17.938 | 1800 | 17.934 | 1906 |
17 | 18.663 | 1200 | 18.614 | 1185 |
18 | 19.821 | 600 | 19.749 | 584 |
校正曲线 | logM = −0.002409928T3 + 0.1095525T2 − 1.823136T + 14.62927 | logM = −0.002151357T3 + 0.09614305T2 − 1.59638T + 13.36678 | ||
相关系数R | 0.99964 | 0.99964 | ||
离差 | 0.0103785 | 0.0100719 |