Co-N-C

0.1 M HClO4

80 mmol gcat−1 h−1 (0.5 VRHE) 275 mmol gcat−1 h−1 (0.4 VRHE)

>90

[12]

Co-POC-O

0.1 M KOH

813 mg L−1 h−1 (100 mA) 478 mmol gcat−1 h−1 (100 mA)

>80

[13]

Ni-N2O2/C

0.1 M KOH

5.9 mol gcat−1 h−1

96

[28]

Co1-NG(O)

0.1 M PBS

-

~70

[29]

0.1 M KOH

~418 mmol gcat−1 h−1 (50 mA)

~82

碳基催化剂

杂原子掺杂

N-石墨(N60.7%)

碱性

1286.9 mmolgcat−1 h−1

~75

[30]

FPC

pH = 1

112.6~792.6 mmol gcat−1 h−1

97.5 - 83

[18]

HPCS-S

-

183.99 mmol gcat−1 h−1 (0.77 VRHE)

~70

[31]

F-mrGO(at RDE)

0.1 M KOH

-

-

[32]

F-mrGO

430.8 mmol gcat−1 h−1 (0.685 VRHE)

~100

F-mrGO(600)

-

~100

N-CMK3-IL

0.1 M KOH

561.7 mmol gcat−1 h−1 (0.1 VRHE)

~86

[16]

氧功能化

O-CNTs

0.1 M KOH

~3950 mg L−1 h−1 (50 mA)

~90

[18]

CNTs

-

~60

oxo-G/NH3H2O

0.1 M KOH

224.8 mmol gcat−1 h−1 (0.2 VRHE)

>82

[33]

rGO-KOH

0.1 M KOH

-

~100

[19]

缺陷

HPC

0.1 M HClO4

395.7~110.2 mmol gcat−1 h−1

80.9 - 95

[21]

CMK-3

0.1 M KOH

0.3 wt% (2 h) (1.6 V,46 mA)

~90

[6]

o-GOMC-1

0.1 M KOH

24 ± 2 mM (16 h, 3 mA)

93 ± 1

[34]

g-N-CHNs

0.1 M H2SO4

-

98

[35]

0.1 M PBS

-

90

0.1 M NaOH

-

63