Complexes

Hdc kOe

Ueff/cm−1

τ0/s

双核

[Dy2(dbm)4(L1)2] (1)

0

23.96

1.54 × 10−7

[Dy2(dbm)2(L2)2] (2)

0

46.94

6.1 × 10−7

[Eu(hfac)2L3]2 (3)

-

-

-

[Tb(hfac)2L3]2 (4)

2

4.67

2.3 × 10−6

[Tb(tfac)2L3]2·(C7H16)x (5)

-

-

-

[Yb(tfac)2L3]2 (6)

-

-

-

[(acac)4Dy 2(L4)] (7)

1

90.9

3.3 × 10−14

[(acac)4Tb 2(L4)] (8)

-

-

-

[(acac)4Ho 2(L4)] (9)

-

-

-

[(acac)4Er 2(L4)] (10)

-

-

-

[(acac)4Gd2(L4)] (11)

-

-

-

[Tb2(L5)2(NO3)4]·2CH3OH (12)

-

-

-

[Dy2(L5)2(NO3)4]·2CH3OH (13)

-

-

-

[Ho2(L5)2(NO3)4]·2CH3OH (14)

-

-

-

[Er2(L5)2(NO3)4]·2CH3OH (15)

-

-

-

[Tm2(L5)2(NO3)4]·2CH3OH (16)

-

-

-

[Yb2(L5)2(NO3)4]·2CH3OH (17)

-

-

-

[Lu2(L5)2(NO3)4]·2CH3OH (18)

-

-

-

[Eu2(acac)4(HL6)2]·3C2H5OH (19)

-

-

-

[Tb2(acac)2(HL6)4]·6C2H5OH (20)

-

-

-

[Dy2(acac)2(HL6)4]·6C2H5OH (21)

0.8

33.63

3.3 × 10−14

[Er2(acac)2(HL6)4]·6C2H5OH (22)

-

-

-

[Yb2(acac)2(HL6)4]·6C2H5OH (23)

-

-

-

[Dy2(bfa)4(HL6)2]·2H2O (24)

0.8

38.07

5.3 × 10−9

[Dy2(tmhd)2(HL6)4] (25)

3

42.08

3.52 × 10−7

[Dy2(MeOH)2(HL9)2(NO3)2]·2MeOH (29)

1

23.6

4.5 × 10−6

四核

[Dy4(L7)4(MeOH)8](NO3)4·aMeOH·bH2O (26)

0

109.7

1.06 × 10−7

[Gd4(L7)4(MeOH)8](NO3)4·aMeOH·bH2O(27)

-

-

-

[Er4(NO3)2(acac)4(L8)2(CH3OH)2]·2CH3CN (28)

-

-

-

五核

[Dy5(L9)4(CH3CO2)6](CH3CO2)·6MeOH·H2O (32)

0.2

27.0

1.21 × 10−9

六核

[Dy6(μ3OH)2(L10)2(HL10)2(H2L10)2Cl2(EtOH)2]Cl2·3EtOH·CH3CN (30)

1

27.77

1.68 × 10−8

[Dy(HL9)2](NO3)·2H2O (31)

0

26.7

6.35 × 10−6

[Dy6(L)2(L9)2(u3-OH)4(CF3SO3)6(EtOH)4]·2EtOH (33)

0

23.3

6.35 × 10−7

dbm = 1,3-diphenyl-1,3-propanedione; L1= 2-[(4-methoxy-phenyl)imino]methyl]-8-hydroxy-quinoline; L2= 2-[[(4-ethoxyphenyl)imino]methyl]-8-hydroxyquinoline; L3=2-[[(4-iodophenyl)imino]methyl]-8-hydroxyquinoline, hfac = hexafluoroacetylacetonate, tfac= trifluoroacetylacetonate; L4= 2,6-diformyl-4-methylphenol; L5 = 6-Methoxy-2-(2-pyridylmethyliminomethyl) phenol; H2L6 = 5-methylsalicylaldehyde-2-aminobenzoylhydrazone; Hacac = acetylacetone; Hbfa = benzoyltrifluoroacetylacetone; Htmhd = 2,2,6,6-tet-ramethylheptane-3,5-dione; H2L7 = (3,6-bis(vanillidenehydrazinyl)-1,2,4,5-tetrazine); H4L8 = (E)-2-(hydroxymethyl)-2-(((2-hydrox-ynaphthalen-1-yl) methylene)amino)propane-1,3-diol, Hacac = acetylacetone; L9 = 3-(((2-hydroxynaphthaen-1-yl)methylene)amino) -propane-1,2-diol; L10= 2-(β-naphthalideneamino)-2-(hydroxylmethyl)-1-propanol; L11= 2-(hydroxymethyl)-6- methoxyphenol)